Absolute CH concentration in flames measured by cavity ring-down spectroscopy

被引:36
|
作者
Derzy, I
Lozovsky, VA
Cheskis, S [1 ]
机构
[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
关键词
D O I
10.1016/S0009-2614(99)00462-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cavity ring-down spectroscopy (CRDS) was used to measure absolute concentration profiles of the CH radical in low-pressure methane/air flames. The Q(1)(4) rotational line of the C(2)Sigma(+) <-- (XII)-I-2 band at 315 nm was used for concentration measurements. Very high sensitivity (2 X 10(10) cm(-3)) is demonstrated. The measured profiles are in good agreement with that calculated using the GRI-Mech mechanism. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:319 / 324
页数:6
相关论文
共 50 条
  • [1] Absolute CH concentration measurements by cavity ring-down spectroscopy in an atmospheric diffusion flame
    Mercier, X
    Jamette, P
    Pauwels, JF
    Desgroux, P
    [J]. CHEMICAL PHYSICS LETTERS, 1999, 305 (5-6) : 334 - 342
  • [2] Cavity Ring-Down Spectroscopy measurements of Acetone concentration
    Revalde, G.
    Alnis, J.
    Nitiss, E.
    Bluss, K.
    Grundsteins, K.
    [J]. XXIII INTERNATIONAL CONFERENCE ON SPECTRAL LINE SHAPES, 2017, 810
  • [3] Cavity ring-down spectroscopy of low concentration gases
    不详
    [J]. JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY, 1996, 101 (03): : 406 - 407
  • [4] Measurement of absolute CH3 concentration in a hot-filament reactor using cavity ring-down spectroscopy
    Wahl, EH
    Owano, TG
    Kruger, CH
    Zalicki, P
    Ma, Y
    Zare, RN
    [J]. DIAMOND AND RELATED MATERIALS, 1996, 5 (3-5) : 373 - 377
  • [5] Measurement of acetylene concentration in laminar flat flames by diode laser cavity ring-down spectroscopy
    P. Otti
    G. S. Humphries
    Y. Hu
    M. Lengden
    I. S. Burns
    [J]. Applied Physics B, 2022, 128
  • [6] Measurement of acetylene concentration in laminar flat flames by diode laser cavity ring-down spectroscopy
    Otti, P.
    Humphries, G. S.
    Hu, Y.
    Lengden, M.
    Burns, I. S.
    [J]. APPLIED PHYSICS B-LASERS AND OPTICS, 2022, 128 (09):
  • [7] Measurements of absolute concentrations of CH in a premixed atmospheric flat flame by cavity ring-down spectroscopy
    Evertsen, R
    Van Oijen, JA
    Hermanns, RTE
    De Goey, LPH
    Ter Meulen, JJ
    [J]. COMBUSTION AND FLAME, 2003, 132 (1-2) : 34 - 42
  • [8] Cavity ring-down spectroscopy
    Zare, RN
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U83 - U83
  • [9] Cavity ring-down spectroscopy
    Wheeler, MD
    Newman, SM
    Orr-Ewing, AJ
    Ashfold, MNR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (03): : 337 - 351
  • [10] Measurement of the absolute intensity of the fifth CH stretching overtone of benzene using cavity ring-down spectroscopy
    Kleine, D
    Stry, S
    Lauterbach, J
    Kleinermanns, K
    Hering, P
    [J]. CHEMICAL PHYSICS LETTERS, 1999, 312 (2-4) : 185 - 190