Synthesis, Structure and Properties of a Porous Ni(II) Coordination Polymer Constructed from 1,1′-(1,4-Butanediyl)bis(imidazole) and o-Phthalate Acid

被引：2

作者：

Gong Wei ^{[1
]}

Niu Qiong ^{[1
]}

Niu He-Lin ^{[1
]}

Hu Lin ^{[2
,3
]}

Mao Chang-Jie ^{[1
]}

Song Ji-Ming ^{[1
]}

Zhang Sheng-Yi ^{[1
]}

Zheng Jun ^{[1
]}

Chen Qian-Wang ^{[2
,3
]}

机构：

[1] Anhui Univ, Coll Chem & Chem Engn, Hefei 230039, Peoples R China

[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[3] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 03期

关键词：

nickel coordination polymer; 1, 1 '-(1,4-butanediyl)bis(imidazole); o-phthalate acid anion; hydrothermal synthesis; crystal structure; gas sorption; METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; NETWORKS; STORAGE;

D O I：

10.3969/j.issn.1001-4861.2013.00.115

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A coordination polymer [Ni(Pht)(bbim-4)](n) (Pht=o-phthalate acid anion,bbim-4=1, 1'-(1, 4-butanediyl) his (imidazole) was synthesized by hydrothermal reaction and characterized by elemental analysis, powder X-ray diffraction, TGA and X-ray single crystal diffraction. The crystal belongs to monoclinic system, space group C2/c. Coordination polymer [Ni (Pht)(bbim-4)](n) is a three-dimensional porous coordination polymer with triangular channels. The coordination polymer shows an overall ferromagnetic behavior. Gas sorption studies suggest that the coordination polymer has selectivity in adsorption of N-2 and CO2 gas. CCDC: 818068.

引用

页码：642 / 648

页数：7

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