4-[(4-Chlorophenyl)(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl) methyl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one

被引:1
|
作者
Fun, Hoong-Kun [1 ]
Jebas, Samuel Robinson [1 ,3 ]
Girish, K. S. [2 ]
Kalluraya, B. [2 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[2] Mangalore Univ, Dept Studies Chem, Mangalore 574199, India
[3] Karunya Univ, Dept Phys, Coimbatore 641114, Tamil Nadu, India
关键词
D O I
10.1107/S1600536808036088
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the the title compound, C27H23ClN4O2, the chloro-phenyl ring forms dihedral angles of 77.70 (9) and 86.65 (9)°, respectively, with the pyrazol-3-one and pyrazole rings. The phenyl rings attached to the pyrazole rings are twisted away from them [dihedral angles 33.80 (9) and 40.34 (10)°]. An intramolecular O - H⋯O hydrogen bond generates an S(8) ring motif. The mol-ecules are linked into chains running along the c axis by N - H⋯N hydrogen bonds, and the chains are cross-linked via C - H⋯O hydrogen bonds and C - H⋯π inter-actions involving the chloro-phenyl ring. © 2008.
引用
收藏
页码:O2301 / U1984
页数:13
相关论文
共 50 条
  • [1] 4-[(5-Hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)phenylmethyl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol hemisolvate
    Fun, Hoong-Kun
    Kia, Reza
    Girish, K. S.
    Kalluraya, B.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O66 - U1836
  • [2] 4-[(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one
    Wang, Jiu-Si
    Jiang, Yan-Ling
    Dong, Wen-Kui
    Xu, Li
    Kong, Ai-Ping
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1794 - U2279
  • [3] 4-[(3-Hydroxy-5-phenyl-1H-pyrazol-4-yl)-methyl]-5-phenyl-1H-pyrazol-3(2H)-one
    Baryala, Yamna
    Zerzouf, Abdelfettah
    Essassi, El Mokhtar
    Reuter, Hans
    Eickmeier, Henning
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2554 - O2556
  • [4] 2-(4-Chlorophenyl)-4-[1-(4-chlorophenyl)-3-methyl-1H-pyrazol-5-yl]-5-methyl-1H-pyrazol-3(2H)-one
    Rabnawaz, Muhammad
    Shah, Muhammad Raza
    Ng, Seik Weng
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2569 - U535
  • [5] 4-(4-Chlorobenzyl)-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one
    Mohamed, Shaaban K.
    El-Remaily, Mahmoud A. A.
    Soliman, Ahmed M.
    Abdel-Ghany, Hossam
    Ng, Seik Weng
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1153 - U679
  • [6] 4-Methyl-5-phenyl-1H-pyrazol-3(2H)-one
    Loh, Wan-Sin
    Fun, Hoong-Kun
    Ragavan, R. Venkat
    Vijayakumar, V.
    Sarveswari, S.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O151 - U2683
  • [7] 2-[(5-Amino-3-methyl-1-phenyl-1H-pyrazol-4-yl)(4-chlorophenyl)methyl]malononitrile
    Zhang, Xin-Ying
    Li, Xiao-Yan
    Wang, Xia
    Li, Dong-Fang
    Fan, Xue-Sen
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O908 - U2546
  • [8] Synthesis, crystal structure, Hirshfeld surface, DFT and docking studies of 4-[(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)(phenyl)methyl]-5-methyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one
    Rajamanickam, Ramachandran
    Sivakolunthu, Senthan
    Sampathkumar, Jayanthi
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2022, 1252
  • [9] 4-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)methylideneamino]-1,5dimethyl-2-phenyl-1H-pyrazol-3(2H)one
    Zhu, Hualing
    Zhu, Jinhua
    Ban, Litong
    Zhang, Pingping
    Zhang, Miao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2724 - U1784
  • [10] CRYSTAL-STRUCTURE OF 4-[5-(5-METHOXY-3-METHYL-1-PHENYL-1H-PYRAZOL-4-YLOXY)-3-METHYL-1-PHENYL-1H-PYRAZOL-4-YL]-6-METHYL-2-PHENYLPYRIDAZIN-3(2H)-ONE
    MANNILA, E
    HENNIG, L
    RISSANEN, K
    [J]. ACTA CHEMICA SCANDINAVICA, 1995, 49 (10): : 774 - 777