Synthesis of Potassium-Magnesium Ate Complexes with a Bulky Diamido Ligand

被引：14

作者：

Pi, Chengfu ^{[1
,2
]}

Wan, Li ^{[1
]}

Gu, Yingying ^{[1
]}

Wu, Haoyu ^{[1
]}

Wang, Chengxi ^{[1
]}

Zheng, Wenjun ^{[1
]}

Weng, Linhong ^{[1
]}

Chen, Zhenxia ^{[1
]}

Yang, Xiaodian ^{[2
]}

Wu, Limin ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 17期

基金：

中国国家自然科学基金;

关键词：

CATION-PI INTERACTIONS; CRYSTAL-STRUCTURE; SODIUM; ARYL; METALATION; REDUCTION; CHEMISTRY; REAGENTS; RECEPTOR; AMIDES;

D O I：

10.1021/om900532v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mixed potassium-magnesium complexes (magnesiates) with novel structural conformations were prepared by the reduction of a neutral magnesium ([(mu-Mg){eta(2):eta(1)-Me2Si(NDipp)(2)}](2)) complex bearing bulky diamido ligands with metallic potassium.

引用

页码：5281 / 5284

页数：4

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