Chemical and electrochemical investigations on thiazolium salts:: a route to powerful donors in the dithiadiazafulvalene series

被引：16

作者：

Bellec, N ^{[1
]}

Guérin, D ^{[1
]}

Lorcy, D ^{[1
]}

Robert, A ^{[1
]}

Carlier, R ^{[1
]}

Tallec, A ^{[1
]}

机构：

[1] Univ Rennes, UMR CNRS 6510, F-35042 Rennes, France

来源：

ACTA CHEMICA SCANDINAVICA | 1999年 / 53卷 / 10期

关键词：

D O I：

10.3891/acta.chem.scand.53-0861

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Thiazolium salts have been investigated, chemically and electrochemically, in order to access to the redox properties of dithiadiazafulvalenes (DTDAF). As these donor molecules are oxygen-sensitive, it is more advisable to isolate them in their oxidized form as dicationic salts. Starting from a tetrathiazolium cation including two precursors groups, linked together with a conjugated spacer, a bis-DTDAF was formed and its electrochemical behavior studied.

引用

页码：861 / 866

页数：6

共 2 条

[1] Chemical and electrochemical investigations on the powerful π-electron donor dithiadiazafulvalene:: Isolation, spectroscopic characterization and charge-transfer complexation
Morel, G
Gachot, G
Lorcy, D
SYNLETT, 2005, (07) : 1117 - 1120
[2] INVESTIGATIONS IN METALLOCENIC SERIES .25. ELECTROCHEMICAL REDUCTION OF (PI-CYCLOPENTADIENYL) (PI-ARENE)FE SALTS, IN AQUEOUS, ALCOHOLIC OR HYDROALCOHOLIC MEDIA
ASTRUC, D
DABARD, R
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE II-CHIMIE MOLECULAIRE ORGANIQUE ET BIOLOGIQUE, 1976, (1-2): : 228 - 232

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