The first crystal structure determination of biphosphole-transition-metal complex: crystal structure of square-planer meso-[Pd(3,3',4,4'-tetramethyl-1,1'-diphenyl-2,2'-biphosphole)2][BF4](2)

被引:6
|
作者
Kojima, T [1 ]
Saeki, K [1 ]
Ono, K [1 ]
Ohba, M [1 ]
Matsuda, Y [1 ]
机构
[1] KYUSHU UNIV,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN
关键词
D O I
10.1039/a702864d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first X-ray crystal structure determination of a biphosphole-transition-metal complex is reported; the square-planar palladium(II) complex has unique intramolecular pi-pi interaction between phenyl groups on chiral phosphorus atoms of two biphosphole ligands.
引用
收藏
页码:1679 / 1680
页数:2
相关论文
共 50 条