Synthesis, Crystal Structure and Thermal Behavior of a New Lead Dimer: [Pb(L)(adip)]2n

被引：0
|
作者：
Jiang Da-Yu [1 ,2 ]
Qi Yan-Li [1 ,2 ]
Liu Yan [1 ,2 ]
Zhou Hui-Jiao [1 ,2 ]
He Wen-Fang [1 ,2 ]
机构：
[1] Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 32卷 / 06期
关键词：
lead complex; crystal structure; dimer; 11-fluoro-dipyrido[3,2-a:2 ',3 '-c]phenazine; ELECTROCHEMICAL PROPERTIES; HYDROTHERMAL SYNTHESIS; COORDINATION;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination compound, [Pb(L)(adip)]2(n) (L = 11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine and H(2)adip = adipic acid), has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. It crystallizes in triclinic, space group P (1) over bar with a = 8.8764(16), b = 9.8088(17), c = 12.948(2) angstrom, alpha = 81.597(3), beta = 80.183(3), gamma = 73.918(3)degrees, V = 1061.5(3) angstrom(3), Z = 2, C24H17FN4O4Pb, M-r = 651.61, D-c = 2.039 g/cm(3), F(000) = 624, mu(MoK alpha) = 7.997 mm(-1), R = 0.0347 and wR = 0.0795. Adjacent Pb(II) atoms are bridged by two adip ligands to furnish a dimer with a long Pb center dot center dot center dot Pb distance of 9.019 angstrom. The lateral L ligands from neighboring dimers are paired through the strong pi-pi interactions, yielding a fascinating 2D supramolecular layer.
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收藏
页码：827 / 830
页数：4
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