First investigation of the electrochemical performance of γ-LiFeO2 micro-cubes as promising anode material for lithium-ion batteries

被引:12
|
作者
Guo, Sheng-Ping [1 ,2 ]
Ma, Ze [1 ]
Li, Jia-Chuang [1 ]
Xue, Huai-Guo [1 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
CATHODE MATERIAL; METAL-OXIDES; STORAGE; LIFEO2;
D O I
10.1007/s10853-016-0441-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The gamma-LiFeO2 micro-cubes were synthesized using a simple solid-state method. Their electrochemical performance as anode material for lithium ion batteries was firstly investigated. Pure gamma-LiFeO2 without nanosizing or carbon coating can deliver the first discharge capacity of 1055.3 mAh/g, and 611.5 mAh/g can be maintained after 50 cycles, around 80 % of the second discharge capacity. gamma-LiFeO2 also demonstrates nice rate capabilities. These results indicate that gamma-LiFeO2 is a promising anode material candidate for lithium ion batteries. The charge/discharge mechanism was also investigated.
引用
收藏
页码:1469 / 1476
页数:8
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