Hansen solubility parameters for supercritical water

被引：35
|
作者：
Marcus, Yizhak [1 ]
机构：
[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel
来源：
JOURNAL OF SUPERCRITICAL FLUIDS | 2012年 / 62卷
关键词：
Hansen solubility parameter; Dispersion; Polarity; Hydrogen bonding; FLUIDS; MIXTURES; MODEL;
D O I：
10.1016/j.supflu.2011.10.018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Expressions are derived for the separate solubility parameters of supercritical water (SCW) due to dispersion, polarity, and hydrogen bonding interactions, in terms of the molar volume of SCW. The molar volumes were calculated from established densities, in turn, and the calculated data are presented as a function of the temperature and the pressure in the ranges relevant to applications of SCW: 400-700 degrees C and 25-100 MPa. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：60 / 64
页数：5
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