Using the Agrawal integral equation to study the thermal degradation of polyvinyl acetate-montmorillonite-dioctadecyl dimethyl ammonium bromide

被引：1

作者：

Fang, Qun ^{[1
]}

Cui, Hui-wan ^{[2
,3
]}

Du, Guan-ben ^{[2
,3
]}

机构：

[1] Zhejiang A&F Univ, Sch Engn, Linan 311300, Peoples R China

[2] Southwest Forestry Univ, Kunming 650224, Yunnan, Peoples R China

[3] Nanjing Forestry Univ, Coll Wood Sci & Technol, Nanjing 210037, Jiangsu, Peoples R China

来源：

JOURNAL OF POLYMER ENGINEERING | 2013年 / 33卷 / 01期

关键词：

nanocomposites; thermal properties; thermodynamics; MECHANICAL-PROPERTIES; NANOCOMPOSITES; PYROLYSIS; KINETICS;

D O I：

10.1515/polyeng-2012-0101

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

To study the pyrolysis kinetics of exfoliated nanocomposites, polyvinyl acetate (PVAc)-montmorillonite (MMT)-dioctadecyl dimethyl ammonium bromide (DOAB) was prepared through five different synthesis processes. The synthesis processes and MMT-DOAB had some effect on the thermal degradation, which was found to consist of eight phases. MMT-DOAB had no significant effect on the pyrolysis temperature, but delayed the thermal degradation process. The pyrolysis kinetics in thermal degradation were analyzed using the Agrawal integral equation.

引用

页码：41 / 47

页数：7

共 8 条

[1] Structure and dynamic mechanical kinetics of polyvinyl acetate-montmorillonite-dioctadecyl dimethyl ammonium bromide
Cui, Hui-wang
Du, Guan-ben
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2013, 26 (09) : 1206 - 1222
[2] Preparation and characterization of exfoliated nano-composite prepared by vinyl acetate, montmorillonite and dioctadecyl dimethyl ammonium bromide
Cui, Huiwang
Du, Guan-ben
E-POLYMERS, 2012,
[3] Using Vinyl Acetate, N-Hydroxymethyl Acrylamide, and Montmorillonite Intercalated by a Dioctadecyl Dimethyl Ammonium Bromide Surfactant to Prepare Exfoliated Nanocomposite through In Situ Polymerization
Cui, Hui-Wang
Fang, Qun
Du, Guan-Ben
ADVANCES IN POLYMER TECHNOLOGY, 2017, 36 (02) : 211 - 219
[4] Using Agrawal integral equation to study the glass transition and cold crystallization kinetics of exfoliated nano-composites synthesized by vinyl acetate and organic montmorillonite
Cui, Hui-wang
Du, Guan-ben
JOURNAL OF COMPOSITE MATERIALS, 2012, 46 (23) : 2951 - 2958
[5] Using Agrawal integral equation to study the pyrolysis kinetics of exfoliated montmorillonite from a polyhedral oligomeric silsesquioxane surfactant and click chemistry
Cui, Hui-Wang
Kuo, Shiao-Wei
APPLIED CLAY SCIENCE, 2014, 101 : 604 - 607
[6] Using Agrawal integral equation and thermogravimetric analysis (TGA) to study the pyrolysis kinetics of nanocomposites of polybenzoxazine and exfoliated montmorillonite from a mono-functionalized azide polyhedral oligomeric silsesquioxane and click chemistry
Hui-Wang Cui
Shiao-Wei Kuo
Polymer Bulletin, 2013, 70 : 3143 - 3153
[7] Using Agrawal integral equation and thermogravimetric analysis (TGA) to study the pyrolysis kinetics of nanocomposites of polybenzoxazine and exfoliated montmorillonite from a mono-functionalized azide polyhedral oligomeric silsesquioxane and click chemistry
Cui, Hui-Wang
Kuo, Shiao-Wei
POLYMER BULLETIN, 2013, 70 (11) : 3143 - 3153
[8] Using Agrawal integral equation, dynamic mechanical analysis (DMA), and differential scanning calorimeter (DSC) methods to study the glass transition kinetics of nanocomposites of polybenzoxazine and exfoliated montmorillonite from a polyhedral oligomeric silsesquioxane surfactant and click chemistry
Cui, Hui-Wang
Kuo, Shiao-Wei
APPLIED CLAY SCIENCE, 2014, 91-92 : 1 - 5

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