Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

被引：85
|
作者：
Shintani, Ryo [1 ]
Maciver, Eleanor E. [1 ]
Tamakuni, Fumiko [1 ]
Hayashi, Tamio [1 ,2 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 41期
关键词：
CROSS-COUPLING REACTIONS; C2-SYMMETRICAL BIS(PHOSPHOLANES); KINETIC RESOLUTION; ARYLBORONIC ACIDS; STEREOCHEMISTRY; DESYMMETRIZATION; HYDROSILYLATION; SILANES; ESTERS; ARYL;
D O I：
10.1021/ja3076555
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through "enantioselective transmetalation".
引用
收藏
页码：16955 / 16958
页数：4
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