Application of Atmospheric-Pressure-Plasma-Jet Modified Flexible Graphite Sheets in Reduced-Graphene-Oxide/Polyaniline Supercapacitors

被引:3
|
作者
Hao, Yu-Chuan [1 ]
Nurzal, Nurzal [1 ]
Chien, Hung-Hua [2 ]
Liao, Chen-Yu [2 ]
Kuok, Fei-Hong [2 ]
Yang, Cheng-Chen [3 ]
Chen, Jian-Zhang [2 ]
Yu, Ing-Song [1 ]
机构
[1] Natl Dong Hwa Univ, Dept Mat Sci & Engn, Hualien 97401, Taiwan
[2] Natl Taiwan Univ, Grad Inst Appl Mech, Taipei 10617, Taiwan
[3] Natl Dong Hwa Univ, Dept Phys, Hualien 97401, Taiwan
关键词
polyaniline; reduced graphene oxide; atmospheric pressure plasma; supercapacitor; graphite sheet; NANOCOMPOSITES; PERFORMANCE; ELECTRODE; ANODE;
D O I
10.3390/polym12061228
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, flexible and low-cost graphite sheets modified by atmospheric pressure plasma jet are applied to reduced-graphene-oxide/polyaniline supercapacitors. Surface treatment by atmospheric pressure plasma jet can make the hydrophobic surface of graphite into a hydrophilic surface and improve the adhesion of the screen-printed reduced-graphene-oxide/polyaniline on the graphite sheets. After the fabrication of reduced-graphene-oxide/polyaniline supercapacitors with polyvinyl alcohol/H(2)SO(4)gel electrolyte, pseudo-capacitance and electrical double capacitance can be clearly identified by the measurement of cyclic voltammetry. The fabricated supercapacitor exhibits specific capacitance value of 227.32 F/g and areal capacitance value of 28.37 mF/cm(2)with a potential scan rate of 2 mV/s. Meanwhile, the capacitance retention rate can reach 86.9% after 1000-cycle cyclic voltammetry test. A light-emitting diode can be lit by the fabricated reduced-graphene-oxide/polyaniline supercapacitors, which confirms that the supercapacitors function well and can potentially be used in a circuit.
引用
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页数:12
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