Oxygen Defect Sn-Doped ZnO Nanorods for Enhanced Photocatalytic Activity under Visible Light Irradiation

被引:20
|
作者
Wang, J. [1 ,2 ]
Sun, X. H. [1 ,2 ]
Du, H. [1 ,2 ]
机构
[1] Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
[2] Xinjiang Key Lab Energy Storage & Photocatalyt Mi, Urumqi 830054, Peoples R China
基金
中国国家自然科学基金;
关键词
Sn doped ZnO; oxygen-vacancy; photocatalytic; DYE; AG; DEGRADATION; PERFORMANCE; HETEROSTRUCTURES; NANOPARTICLES; FABRICATION; NANOSHEETS;
D O I
10.1134/S0036023620070244
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Sn doped ZnO (SZO) nanorods with oxygen-vacancy have been synthesized by one-step hydrothermal method. Detailed analysis based on X-ray photoelectron spectroscopy (XPS), transmission electron microscope (HRTEM), and electron paramagnetic resonance (EPR) has revealed that Sn doped ZnO nanorods are rich in oxygen-vacancies. Oxygen-vacancies lead to the band-gap narrowing of Sn doped ZnO nanorods due to broadening the valence band and an increase the visible-light response which results in high photocurrent responses and photocatalytic performance of Rhodamine B under visible-light illumination. Sn doped ZnO sample exhibits little decrease in activity even after 4 cycles, indicating that Sn doped ZnO is stable and not photocorroded easily.
引用
收藏
页码:1111 / 1118
页数:8
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