Trifluoroacetic acid catalyzed tetrahydropyranylation of alcohols and phenols and direct conversion of THP ethers into acetates

被引：0
|
作者：
Bodipati, Naganjaneyulu [1 ]
Palla, Srinivasa Rao [1 ]
Peddinti, Rama Krishna [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2012年 / 51卷 / 02期
关键词：
Tetrahydropyranylation; trifluoroacetic acid; alcohols; phenols; THP ethers; acetates; SOLVENT-FREE TETRAHYDROPYRANYLATION; ONE-STEP CONVERSION; EFFICIENT CATALYST; HIGHLY EFFICIENT; CHEMOSELECTIVE TETRAHYDROPYRANYLATION; SYNTHETIC PROTOCOL; MILD; DEPROTECTION; TRIFLATE; CHLORIDE;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple procedure for tetrahydropyranylation of alcohols and phenols in dichloromethane and their depyranylation in methanol in the presence of trifluoroacetic acid at ambient temperature is described. This methodology is useful for substrates having functionalities such as ester, amide, nitro, aldehyde and olefinic bonds. Trifluoroacetic acid mediated direct conversion of tetrahydropyranyl ethers into their corresponding acetates is also described.
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页码：356 / 361
页数：6
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