Reactions at solid-liquid interfaces:: contrasting chemistry at different crystal faces in the hydroxide-induced reactive dissolution of p-chloranil as revealed by channel flow cell voltammetry

被引：2

作者：

Hill, E

Lloyd-Williams, RR

Compton, RG

Atherton, JH

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Zeneca Huddersfield Works, Huddersfield HD2 1FF, W Yorkshire, England

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 1999年 / 3卷 / 06期

关键词：

p-chloranil; channel flow cell; solid/liquid interface;

D O I：

10.1007/s100080050162

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The (100), (010) and (001) faces of monoclinic crystals of the organic solid p-chloranil display contrasting reactivities towards hydrolytic dissolution induced by aqueous hydroxide ions. The differing behaviour is rationalised in terms of the functional groups exposed in the different faces.

引用

页码：327 / 330

页数：4

共 2 条

[1] Reactions at solid-liquid interfaces: contrasting chemistry at different crystal faces in the hydroxide-induced reactive dissolution of p-chloranil as revealed by channel flow cell voltammetry
Emma Hill
Richard R. Lloyd-Williams
Richard G. Compton
John H. Atherton
Journal of Solid State Electrochemistry, 1999, 3 : 327 - 330
[2] Mechanism of solid|liquid interfacial reactions.: The reactive dissolution of p-chloranil in aqueous solution as studied by the channel flow cell with electrochemical detection and atomic force microscopy
Booth, J
Sanders, GHW
Compton, RG
Atherton, JH
Brennan, CM
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 440 (1-2): : 83 - 93

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