Control over Catenation in Pillared Paddlewheel Metal-Organic Framework Materials via Solvent-Assisted Linker Exchange

被引：125
|
作者：
Bury, Wojciech [1 ,2 ,3 ]
Fairen-Jimenez, David [4 ,5 ]
Lalonde, Marianne B. [1 ,2 ]
Snurr, Randall Q. [4 ]
Farha, Omar K. [1 ,2 ]
Hupp, Joseph T. [1 ,2 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[3] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland
[4] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[5] Univ Cambridge, Dept Chem Engn & Biotechnol, Cambridge CB2 3RA, England
来源：
CHEMISTRY OF MATERIALS | 2013年 / 25卷 / 05期
关键词：
catenation; metal-organic frameworks; SALE; linker exchange; POSTSYNTHETIC LIGAND; RATIONAL DESIGN; SURFACE-AREA; STRATEGY; INTERPENETRATION; PURIFICATION; POROSITY; STORAGE; SOLIDS; ROUTE;
D O I：
10.1021/cm303749m
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4'-bipyridine (L4) and 4,4'-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.
引用
收藏
页码：739 / 744
页数：6
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