Solution nuclear magnetic resonance spectral characterization of iron(II) porphyrin complexes of weakly coordinating anions

被引：0

作者：

Song, BH ^{[1
]}

Park, B ^{[1
]}

Han, CH ^{[1
]}

机构：

[1] Sun Moon Univ, Dept Chem, Asan 336708, Chungnam, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2002年 / 23卷 / 01期

关键词：

anion binding; iron porphyrin;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Weakly coordinating anions show little affinity for binding to unfunctionalized iron(II) porphyrins. The electron-deficient 5, 10, 15, 20-tetrakis(pentafluorophenyl)porphinatoiron(II) compound is utilized in this study to demonstrate solution coordination by chloride, bromide and acetate ions. The binding strength of anions to the iron(II) porphyrin is reflected by a systematic change in pyrrole proton chemical shift in H-1 NMR spectra; the pyrrole resonance moves downfield when the sigma-donor ability of anions is decreased.

引用

页码：119 / 122

页数：4

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