Characteristics of Asphaltenes Thin Film Extracted from Crude-Oil-Tank-Bottom-Sludge (COTBS)

被引:2
|
作者
Thulasiraman, Sundarajoo [1 ]
Yunus, Noor Mona Md. [2 ]
Kumar, Pradeep [1 ]
Burhanudin, Zainal Arif [1 ]
Wilfred, Cecilia Devi [3 ]
Ariffin, Azhar [4 ]
Hamdan, Mohamad Faizal [5 ]
Hamid, Nor Hisham [6 ]
机构
[1] Univ Teknol Petronas, Dept Elect & Elect Engn, Ctr Innovat Nanostruct & Nanodevices, Seri Iskandar, Perak, Malaysia
[2] Univ Teknol Petronas, Ctr Res Ion Liquids, Seri Iskandar, Perak, Malaysia
[3] Univ Teknol Petronas, Ctr Res Ion Liquids, Dept Fundamental & Appl Sci, Seri Iskandar, Perak, Malaysia
[4] Univ Malaya, Dept Chem, Kuala Lumpur, Malaysia
[5] Petr Nas Berhad, Grp Tech Solut Dept, Technol & Engn Div, Kuala Lumpur, Malaysia
[6] Univ Teknol Petronas, Dept Elect & Elect Engn, Seri Iskandar, Perak, Malaysia
关键词
sludge; asphaltene; thin film; conductivity; ELECTRICAL-CONDUCTIVITY;
D O I
10.1109/rsm46715.2019.8943531
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Asphaltene from Crude-Oil-Tank-Bottom-Sludge (COTBS) was extracted using Soxhlet method. Extracted asphaltene was a mixture of powder with approximately similar to 5 mm shiny chunks. Using elemental analysis, it was confirmed that the extraction resulted in asphaltene dominated by carbon and hydrogen, with 71 and 12 percentage weight, respectively. In thin film form, from ultraviolet - visible (UV-Vis) spectroscopy, its band gap was found to be 2.5 eV. The film, however, had voids and aggregations made visible through scanning electron microscope (SEM). The sheet resistance, resistivity and conductivity of the film were measured to be 1.38x10(11) Omega/similar to, 2.21x10(8)Omega.cm and 4.80x10(-9) S/cm, respectively. From this preliminary data, unless its conductivity can be systematically engineered, it appears that the asphaltene thin film may only be suitable as an insulator.
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页码:42 / 45
页数:4
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