Chamomile (Matricaria recutita) Extract as a Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution

被引:20
|
作者
Nasibi, Mahdi [1 ,2 ]
Zaarei, Davood [3 ]
Rashed, Gholamreza [1 ]
Ghasemi, Effat [4 ]
机构
[1] PUT, Tech Inspect Engn Dept, Abadan, Iran
[2] NIORDC, Hlth & Safety Engn HSE Off, Yazd Zone, Yazd, Iran
[3] Islamic Azad Univ, S Tehran Branch, Tech Fac, Dept Polymer, Tehran, Iran
[4] Ferdowsi Univ Mashhad, Dept Chem Engn, Mashhad, Iran
关键词
Chamomile extract; Corrosion; Corrosion inhibitors; Green inhibitors; Mild steel; Natural product; LOW-CARBON STEEL; M HCL SOLUTION; AQUEOUS EXTRACT; PLANT-EXTRACT; METALS; MEDIA; ADSORPTION; QUERCETIN;
D O I
10.1080/00986445.2012.709475
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The corrosion inhibition of mild steel in hydrochloric acid solution by chamomile (Matricaria recutita) extract (CE) was investigated through electrochemical (polarization, EIS) and surface analysis (optical microscopy/AFM/SEM) techniques. The effects of inhibitor concentration, temperature, and pH were evaluated. Thermodynamic parameters were calculated and adsorption studies were carried out. Finally, the surface morphology was investigated. The electrochemical studies showed that CE acts as a mixed-type corrosion inhibitor with predominantly anodic behavior. CE was adsorbed physically on the metal surface and obeyed the Langmuir adsorption isotherm. It impeded the corrosion processes by changing the activation energy. In the presence of CE, the metal surface was more uniform than the surface in the absence of inhibitor. Maximum inhibition efficiency (IE) was 93.28%, which was obtained at 22 degrees C in 7.2 g/L of inhibitor in 1 M HCl solution.
引用
收藏
页码:367 / 378
页数:12
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