Aziridine Nitrogen Inversion by Dynamic NMR: Activation Parameters in a Fused Bicyclic Structure

被引：5

作者：

de Loera, Denisse ^{[1
]}

Liu, Fang ^{[1
]}

Houk, K. N. ^{[1
]}

Garcia-Garibay, Miguel A. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 22期

基金：

美国国家科学基金会;

关键词：

NUCLEAR-MAGNETIC-RESONANCE; STEREOSELECTIVE-SYNTHESIS; PYRAMIDAL INVERSION; RING; STEREODYNAMICS; SPECTROSCOPY; SUBSTITUENTS; SPECTRA; ENERGY; RATES;

D O I：

10.1021/jo4022315

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The nitrogen inversion of a N-phenyl aziridine fused to a succinimide ring is influenced by the presence of a phenyl ring in the succinimide moiety. The endo invertomer is favored, showing an unsymmetrical equilibrium in variable H-1 NMR studies.

引用

页码：11623 / 11626

页数：4

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