Lanthanide corroles: a new class of macrocyclic lanthanide complexes

被引：45

作者：

Buckley, Heather L. ^{[1
]}

Anstey, Mitchell R. ^{[2
]}

Gryko, Daniel T. ^{[3
,4
]}

Arnold, John ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Sandia Natl Labs, Livermore, CA 94550 USA

[3] Polish Acad Sci, Inst Organ Chem, Warsaw, Poland

[4] Warsaw Univ Technol, Fac Chem, Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 30期

基金：

美国能源部;

关键词：

PORPHYRIN COMPLEXES; METAL-COMPLEXES; CHEMISTRY; IONS; 5,10,15-TRIS(PENTAFLUOROPHENYL)CORROLE; LUMINESCENCE; LIGANDS; REAGENT; PROBES; CERIUM;

D O I：

10.1039/c3cc38806a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes(2)(p-OMePh)corrole)La center dot 4.5DME (1 center dot 4.5DME) and (Mes(2)(p-OMePh)corrole) Tb center dot 4DME (2 center dot 4DME) are prepared from the free base corrole and Ln((NSiMe3)(2))(3), while (Mes(2)(p-OMePh)corrole)-Gd center dot TACNMe(3) (3 center dot TACNMe(3)) is prepared by metathesis of the recently reported Li-3 corrole and GdCl3.

引用

页码：3104 / 3106

页数：3

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