Palladium-catalyzed Suzuki-Miyaura coupling with aryl and heteroaryl bromides using N,N,N′,N′-tetra(diphenylphosphinomethyl)-1,2-ethylenediamine

被引：17
|
作者：
Wang, Kun [1 ]
Yi, Tao [1 ]
Yu, Xiaojun [1 ]
Zheng, Xueli [1 ]
Fu, Haiyan [1 ]
Chen, Hua [1 ]
Li, Ruixiang [1 ]
机构：
[1] Sichuan Univ, Dept Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2012年 / 26卷 / 07期
关键词：
Suzuki-Miyaura coupling; palladium; tetraphosphine; HIGHLY EFFICIENT CATALYST; ARYLBORONIC ACIDS; HECK CATALYSIS; BORONIC ACIDS; COMPLEXES; TETRAPHOSPHINE; LIGAND; PHOSPHINE; HALIDES; SYSTEM;
D O I：
10.1002/aoc.2869
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An easily prepared tetraphosphine N,N,N',N'-tetra(diphenylphosphinomethyl)-1,2-ethylenediamine (1) combined with PdCl2 affords an efficient catalytic system for Suzuki cross-coupling of aryl and heteroaryl bromides. A high turnover number of 750 000 is obtained with the catalyst loading as low as 1?ppm. This catalyst system exhibits good stability and longevity. In this study, a broad scope of substrates is investigated and satisfactory yields are obtained. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码：342 / 346
页数：5
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