Synthesis and crystal structures of two new Schiff base cobalt(II) and nickel(II) complexes

被引:3
|
作者
Gou, Y. [1 ]
Liu, Y. [1 ]
Zhao, X. H. [1 ]
Li, Y. G. [1 ]
Chen, W. [1 ]
机构
[1] Wuhan Text Univ, Sch Chem & Chem Engn, Sch Text Engn, Wuhan 430073, Peoples R China
基金
美国国家科学基金会;
关键词
METAL-COMPLEXES; PI INTERACTIONS; HYDROGEN-BOND; COPPER(II); NI; COORDINATION; CATALYSIS; LIGANDS; POLYMERS; UREASE;
D O I
10.1134/S1070328412120019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Schiff base ligand (HL) obtained from phenylmethanamine and 5-methoxysalicylaldehyde are used as ligands for Co(II) and Ni(II) resulting in complexes [Co(L)(2)] (I) and [Ni(L)(2)] (II), and their solid state structures were determined by X-ray crystallography. In both complexes, weak interactions play an important role in the molecular self-assembly. Complex I was stacked up to the 2D layers by C-HaEuro broken vertical bar O hydrogen bonds and C-HaEuro broken vertical bar pi interactions. In contrast, complex II was extended into 2D sheet by C-HaEuro broken vertical bar O hydrogen bonds, the C-HaEuro broken vertical bar pi interactions, and edge-to-face interactions.
引用
收藏
页码:134 / 140
页数:7
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