Synthesis and crystal structures of two new Schiff base cobalt(II) and nickel(II) complexes

被引：3

作者：

Gou, Y. ^{[1
]}

Liu, Y. ^{[1
]}

Zhao, X. H. ^{[1
]}

Li, Y. G. ^{[1
]}

Chen, W. ^{[1
]}

机构：

[1] Wuhan Text Univ, Sch Chem & Chem Engn, Sch Text Engn, Wuhan 430073, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 01期

基金：

美国国家科学基金会;

关键词：

METAL-COMPLEXES; PI INTERACTIONS; HYDROGEN-BOND; COPPER(II); NI; COORDINATION; CATALYSIS; LIGANDS; POLYMERS; UREASE;

D O I：

10.1134/S1070328412120019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Schiff base ligand (HL) obtained from phenylmethanamine and 5-methoxysalicylaldehyde are used as ligands for Co(II) and Ni(II) resulting in complexes [Co(L)(2)] (I) and [Ni(L)(2)] (II), and their solid state structures were determined by X-ray crystallography. In both complexes, weak interactions play an important role in the molecular self-assembly. Complex I was stacked up to the 2D layers by C-HaEuro broken vertical bar O hydrogen bonds and C-HaEuro broken vertical bar pi interactions. In contrast, complex II was extended into 2D sheet by C-HaEuro broken vertical bar O hydrogen bonds, the C-HaEuro broken vertical bar pi interactions, and edge-to-face interactions.

引用

页码：134 / 140

页数：7

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