Base-Free Cu(II)-Catalyzed Coupling Reaction of Arylboronic Acids and Thiols

被引：9

作者：

Yang, Minghua ^{[1
]}

Pei, Ji ^{[1
]}

Yan, Guobing ^{[1
]}

Weng, Qiuyue

机构：

[1] Lishui Univ, Coll Sci, Lishui 323000, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 33卷 / 02期

关键词：

coupling reaction; thiol; arylboronic acid; 1,10-phenanthroline; cupric acetate; BORONIC ACIDS; ARYL IODIDES; C-O; ORGANOBORONIC ACIDS; CATALYZED SYNTHESIS; S-ARYLATION; EFFICIENT; LIGAND; BOND; DIAZAPHOSPHOLANE;

D O I：

10.6023/cjoc201209008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Baes-free Cu(II)-catalyzed coupling reaction of arylboronic acid and thiols was described. After optimization of reaction conditions, such as solvents, reaction temperatures, copper salts and ligands, the results show that some biarylsulfides were synthesized in good yields using 1,10-phenanthroline-Cu(OAc)2 center dot H2O as catalyst, DMSO/H2O (V : V=1 : 1) as solvent, under air atmosphere at 60 degrees C.

引用

页码：343 / 347

页数：5

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