Overall performance of natural rubber/graphene nanocomposites

被引:185
|
作者
Hernandez, Marianella [1 ]
del Mar Bernal, Maria [1 ]
Verdejo, Raquel [1 ]
Ezquerra, Tiberio A. [2 ]
Lopez-Manchado, Miguel A. [1 ]
机构
[1] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
[2] CSIC, Inst Estruct Mat, E-28006 Madrid, Spain
关键词
Nanocomposites; Mechanical properties; Electrical properties; Graphene; CARBON NANOTUBES; ELECTRICAL-CONDUCTIVITY; FUNCTIONALIZED GRAPHENE; UNIAXIAL DEFORMATION; MOLECULAR-DYNAMICS; RUBBER; REINFORCEMENT; SPECTROSCOPY; COMPOSITES; NETWORKS;
D O I
10.1016/j.compscitech.2012.08.012
中图分类号
TB33 [复合材料];
学科分类号
摘要
Natural rubber (NR) and functionalized graphene sheets (FGSs) nanocomposites were prepared by conventional two-roll mill mixing. The morphology and structure of the FGS was characterized confirming the successful exfoliation of the FGS. The strong rubber-to-filler interactions accelerate the cross-linking reaction, increase the electrical conductivity and cause an important enhancement on the mechanical behavior of the NR nanocomposites. The nanofiller does not affect the molecular dynamics of NR, while the presence of vulcanizing additives slowdowns the segmental motions and decreases slightly the time scale of the global chain dynamics in NR/FGS nanocomposites. These functional properties make NR/FGS nanocomposites a promising new class of advanced materials. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:40 / 46
页数:7
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