Solvent-free mechanochernical chlorination of hydrocarbons with CuCl2

被引：2

作者：

Visnovsky, Jozef ^{[1
,2
]}

Billik, Peter ^{[3
,4
]}

Kubinec, Robert ^{[1
]}

Podolec, Peter ^{[1
]}

Szabo, Alexandra Hengerics ^{[1
]}

Juriga, Martin ^{[5
]}

Cabala, Radomir ^{[6
]}

Kubincova, Janka ^{[7
]}

Blasko, Jaroslav ^{[1
]}

机构：

[1] Comenius Univ, Inst Chem, Fac Nat Sci, Bratislava 84215, Slovakia

[2] SynthCluster SRO, Modra 90001, Slovakia

[3] Comenius Univ, Dept Inorgan Chem, Fac Nat Sci, Bratislava 84215, Slovakia

[4] Slovak Acad Sci, Dept Magnetometry, Inst Measurement Sci, Bratislava 84104, Slovakia

[5] Slovak Univ Technol Bratislava, Inst Chem & Hydraul Machines & Equipment, Fac Mech Engn, Bratislava 81231, Slovakia

[6] Charles Univ Prague, Dept Analyt Chem, Fac Sci, Prague 12843 2, Czech Republic

[7] Comenius Univ, Fac Pharm, Dept Chem Theory Drugs, Bratislava 83232, Slovakia

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 52期

关键词：

Mechanochemistry; High-energy ball milling; Chlorination; Hydrocarbons; CuCl2; MECHANOCHEMICAL DECHLORINATION; AROMATIC-HYDROCARBONS; MILLS;

D O I：

10.1016/j.tetlet.2013.10.108

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solvent-free chlorination of biphenyl and naphthalene was performed under mechanochemical stressing by high-energy ball milling (HEM) of a mixture of CuCl2 (95 wt %) and the hydrocarbon (5 wt %). The reactivity of the selected hydrocarbons towards CuCl2 during HEM partially correlates with their ionisation potentials (IP): hexadecane (9.91 eV) > biphenyl (8.27 eV) > naphthalene (8.14 eV). (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：7180 / 7182

页数：3

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