Heterogenized Fe(III) phthalocyanine: Synthesis, characterization and application in liquid-phase oxidation of phenol

被引：27
|
作者：
Sirotin, Sergey V. [1 ]
Tolbin, Alexander Yu. [1 ,2 ]
Moskovskaya, Irina F. [1 ]
Abramchuk, Sergey S. [1 ]
Tomilova, Larisa G. [1 ,2 ]
Romanovsky, Boris V. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Russian Acad Sci, Inst Physiol Act Cpds, Chernogolovka 142432, Moscow Region, Russia
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2010年 / 319卷 / 1-2期
基金：
俄罗斯基础研究基金会;
关键词：
MCM-41; SBA-15 molecular sieves; Iron(III) phthalocyanines; Hydroxylation of phenol; CATALYTIC PROPERTIES; IRON TETRASULFOPHTHALOCYANINE; SPECTRAL PROPERTIES; MOLECULAR-SIEVES; SILICA-GEL; SURFACE; CYCLOHEXANE; COMPLEXES; CARRIERS; PORES;
D O I：
10.1016/j.molcata.2009.11.017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Tetra-tort-butyl substituted FePc(acac) complexes were supported upon mesoporous molecular sieves MCM-41 and SBA-15 via adsorption and coordination bondings as well as by covalent grafting. Prepared materials were characterized by UV-vis, MALDI, N-2-BET, SEM, TEM, FTIR, C-13, Si-29 NMR and DSC-TG techniques. Supported FePcs exhibited high activity in liquid-phase oxidation of phenol with H2O2. The most resistant towards oxidative degradation were shown to be the covalently grafted FePc species. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：39 / 45
页数：7
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