Copper-Catalyzed Synthesis of α-Thioaryl Carbonyl Compounds Through S-S and C-C Bond Cleavage

被引：75

作者：

Zou, Liang-Hua ^{[1
]}

Priebbenow, Daniel L. ^{[1
]}

Wang, Long ^{[1
]}

Mottweiler, Jakob ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 13期

关键词：

alpha-arylthio esters; alpha-arylthio ketones; CC bond cleavage; copper catalysis; diaryl disulfides; EFFICIENT SYNTHESIS; ACTIVATION; SULFENYLATION; HALIDES; KETONES; THIOLATION; THIOETHERS; ALDEHYDES; INSERTION; SULFIDES;

D O I：

10.1002/adsc.201300566

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A method to access -thioaryl ketones and -thioaryl esters employing copper acetate (hydrate) as catalyst and readily accessible diaryl disulfides and -diketones (or -keto esters) has been developed. Both alkyl- and aryl-substituted carbonyl compounds can be prepared.

引用

页码：2558 / 2563

页数：6

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