Ru(II)-catalyzed intermolecular C-H amidation of weakly coordinating ketones

被引：137
|
作者：
Zheng, Qing-Zhong [1 ]
Liang, Yu-Feng [1 ]
Qin, Chong [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
[2] Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 50期
基金：
美国国家科学基金会;
关键词：
ALKYL ARYL KETONES; AROMATIC KETONES; MULTIPLE ARYLATION; BOND ACTIVATION; CARBONYL-COMPOUNDS; PALLADIUM; OXYGENATION; DERIVATIVES; CLEAVAGE; INDOLES;
D O I：
10.1039/c3cc42613k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient Ru(II)-catalyzed intermolecular amidation of weakly coordinating ketones with sulfonyl azides via C-H bond activation is described. The reaction proceeds with high functional group tolerance, providing a novel approach to practical ketone-directed intermolecular C-N bond formation in the absence of an additional oxidant.
引用
收藏
页码：5654 / 5656
页数：3
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