Luminescent Complexes Containing Halogeno-bridged Dicopper(I) Unit {Cu2(μ-X)2} (X = Cl, Br, and I)

被引：68

作者：

Tsuge, Kiyoshi ^{[1
]}

机构：

[1] Toyama Univ, Grad Sch Sci & Engn, Toyama 9308555, Japan

来源：

CHEMISTRY LETTERS | 2013年 / 42卷 / 03期

关键词：

COPPER(I) HALIDE-COMPLEXES; FLEXIBLE THIOETHER LIGAND; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; THERMOCHROMIC-LUMINESCENCE; PHOTOPHYSICAL PROPERTIES; CRYSTAL-STRUCTURES; STRUCTURAL MOTIFS; IODIDE CLUSTERS; CU-I;

D O I：

10.1246/cl.2013.204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Luminescent copper(I) complexes have been extensively studied in recent decades with various ligands showing their rich photophysical and photochemical properties. In this contribution, the luminescent halogeno copper(I) complexes, especially those with a halogeno-bridged dicopper(I) unit {Cu-2(mu-X)(2)}, one of the basic, common structural motifs among the halogeno copper(I) family, are described from the view point of influences of coligands upon their luminescent properties. Discussions are extended to complexes with the halogeno-bridged tetranuclear unit {Cu-4(mu(3)-X)(4)}, being another common structural motif, to examine the dominant emissive excited states in halogeno copper(I) complexes.

引用

页码：204 / 208

页数：5

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