Syntheses of diruthenaborane clusters, [{CPRu(μ-H)}2B3H7], [{(CpRu)2(μ-H)}B4H9], and [(Cp*Rn)2(μ-H)(PMe3)(μ-η4-B2H5)]

被引：0

作者：

Kawano, Y ^{[1
]}

Matsumoto, H ^{[1
]}

Shimoi, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diruthenapentaborane cluster [{Cp*Ru(mu-H)}(2)B3H7] (1) was synthesized by the reaction of [Cp*RuCl](4) with BH3. THF. Compound 1 undergoes cluster expansion by further interaction with BH3. THF to give [{(Cp*Ru)(2)(mu-H)}B4H9] (2). Reaction of 1 with PMe3 leads to degradation of the cluster framework to give [{(Cp*Ru)(2)(mu-H)}(PMe3)(mu-eta(4)-B2H5)] (3).

引用

页码：489 / 490

页数：2

共 50 条

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Syntheses of diruthenaborane clusters, [{CP*Ru(μ-H)}2B3H7], [{(Cp*Ru)2(μ-H)}B4H9], and [(Cp*Rn)2(μ-H)(PMe3)(μ-η4-B2H5)]

Syntheses of diruthenaborane clusters, [{CPRu(μ-H)}2B3H7], [{(CpRu)2(μ-H)}B4H9], and [(Cp*Rn)2(μ-H)(PMe3)(μ-η4-B2H5)]