Mechanochemical synthesis of Cu(i)-N-heterocyclic carbene complexes

被引：35
|
作者：
Pisano, Gianmarco [1 ,2 ]
Cazin, Catherine S. J. [1 ,2 ]
机构：
[1] Univ Ghent, Dept Chem, Krijgslaan 281,S-3, B-9000 Ghent, Belgium
[2] Univ Ghent, Ctr Sustainable Chem, Krijgslaan 281,S-3, B-9000 Ghent, Belgium
来源：
GREEN CHEMISTRY | 2020年 / 22卷 / 16期
关键词：
N-HETEROCYCLIC CARBENE; NHC; COPPER; MECHANOSYNTHESIS; PERSPECTIVE; ACCESS;
D O I：
10.1039/d0gc01923b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range of NHC ligand precursors, allowing access to complexes of the type [Cu(Cl)(NHC)] under aerobic conditions and with minimised environmental impact.
引用
收藏
页码：5253 / 5256
页数：4
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