The effect of Mo6S3I6 nanowires on the thermal and mechanical properties of polyamide 12

被引:2
|
作者
Huskic, M. [1 ,2 ]
Sever-Skapin, A. [3 ]
Vengust, D. [4 ]
Mihailovic, D. [4 ]
机构
[1] Natl Inst Chem, Ljubljana 1000, Slovenia
[2] Ctr Excellence PoliMaT, Ljubljana 1000, Slovenia
[3] Slovenian Natl Bldg & Civil Engn Inst, Ljubljana 1000, Slovenia
[4] Jozef Stefan Inst, Ljubljana 1000, Slovenia
关键词
Nano-structures; Mechanical properties; Thermal properties; Electron microscopy; CRYSTALLIZATION BEHAVIOR; NANOCOMPOSITES;
D O I
10.1016/j.compositesb.2013.08.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocomposites consisting of PA12 and Mo6S3I6 nanowires at concentrations of 0.5, 1.0 and 2.0 wt.% were prepared by extrusion and characterised. Using electron microscopy it was confirmed that bundles of nanowires were present, whose size increases with increasing concentrations. Differential dynamic calorimetry showed that the nanowires act as a nucleating agent, increasing the crystallization rate and the overall degree of crystallinity, but at the same time the size of the crystals is decreased. As a result, Young's modulus was increased by 15% with the addition of only 0.5 wt.% of Mo6S3I6. The improved mechanical properties are attributed to changes in the polymer morphology and crystallinity. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:62 / 67
页数:6
相关论文
共 50 条
  • [1] Optical properties of Mo6S3I6 nanowires
    Vengust, D.
    Pfuner, F.
    Degiorgi, L.
    Vilfan, I.
    Nicolosi, V.
    Coleman, J. N.
    Mihailovic, D.
    PHYSICAL REVIEW B, 2007, 76 (07)
  • [2] Mo6S3I6 nanowires
    Vrbanic, D
    Meden, A
    Jancar, B
    Ponikvar, M
    Novosel, B
    Venturini, P
    Pejovnik, S
    Mihailovic, D
    ELECTRONIC PROPERTIES OF SYNTHETIC NANOSTRUCTURES, 2004, 723 : 423 - 426
  • [3] Effect of Mo6S3I6 nanowires on the dielectric properties of poly(ε-caprolactone)
    Svirskas, Sarunas
    Jablonskas, Dziugas
    Samulionis, Vytautas
    Kupreviciute, Auste
    Banys, Juras
    Chin, Seow Jecg
    McNally, Tony
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2013, 210 (11): : 2272 - 2277
  • [4] Conducting properties of single bundles of Mo6S3I6 nanowires
    Uplaznik, M
    Mrzel, A
    Vrbanic, D
    Panjan, P
    Podobnik, B
    Mihailovic, D
    ELECTRONIC PROPERTIES OF SYNTHETIC NANOSTRUCTURES, 2004, 723 : 419 - 422
  • [5] Nonlinear elastic and electronic properties of Mo6S3I6 nanowires
    Vilfan, I.
    Mihailovic, D.
    PHYSICAL REVIEW B, 2006, 74 (23):
  • [6] Tribological performances of Mo6S3I6 nanowires
    Dassenoy, F.
    Joly-Pottuz, L.
    Martin, J. M.
    Vrbanic, D.
    Mrzel, A.
    Mihailovic, D.
    Vogel, W.
    Montagnac, G.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (2-3) : 915 - 919
  • [7] Electrical conductivity of Mo6S3I6 and Mo6S4.5I4.5 nanowires
    Vrbanic, D.
    Pejovnik, S.
    Mihailovic, D.
    Kutnjak, Z.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (2-3) : 975 - 978
  • [8] Dispersion and purification of Mo6S3I6 nanowires in organic solvents
    McCarthy, Denis N.
    Nicolosi, Valeria
    Vengust, Damjan
    Mihailovic, Dragan
    Compagnini, Giuseppe
    Blau, Werner J.
    Coleman, Jonathan N.
    JOURNAL OF APPLIED PHYSICS, 2007, 101 (01)
  • [9] Dispersion and purification of Mo6S3I6 nanowires in organic solvents
    McCarthy, Denis N.
    Nicolosi, Valeria
    Vengust, Damjan
    Mihailovic, Dragan
    Compagnini, Giuseppe
    Blau, Werner J.
    Coleman, Jonathan N.
    Journal of Applied Physics, 2007, 101 (01):
  • [10] Air-stable monodispersed Mo6S3I6 nanowires
    Vrbanic, D
    Remskar, M
    Jesih, A
    Mrzel, A
    Umek, P
    Ponikvar, M
    Jancar, B
    Meden, A
    Novosel, B
    Pejovnik, S
    Venturini, P
    Coleman, JC
    Mihailovic, D
    NANOTECHNOLOGY, 2004, 15 (05) : 635 - 638