A Modular Strategy for Fully Conjugated Donor-Acceptor Block Copolymers

被引：119

作者：

Ku, Sung-Yu ^{[1
,5
]}

Brady, Michael A. ^{[1
,2
]}

Treat, Neil D. ^{[1
,2
]}

Cochran, Justin E. ^{[1
,3
]}

Robb, Maxwell J. ^{[1
,3
]}

Kramer, Edward J. ^{[1
,2
,4
,5
]}

Chabinyc, Michael L. ^{[1
,2
,5
]}

Hawker, Craig J. ^{[1
,2
,3
,5
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA

[3] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[4] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

[5] Univ Calif Santa Barbara, Mitsubishi Chem Ctr Adv Mat, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 38期

基金：

美国国家科学基金会;

关键词：

HETEROJUNCTION SOLAR-CELLS; PHOTOVOLTAIC APPLICATIONS; DIBLOCK COPOLYMER; ROD-COIL; POLYMERS; EFFICIENCY; NANOSTRUCTURES; SEMICONDUCTORS; TECHNOLOGY; BLEND;

D O I：

10.1021/ja307431k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel strategy for the synthesis of fully conjugated donor acceptor block copolymers, in a single reaction step employing Stille coupling polymerization of end-functional polythiophene and AA + BB monomers, is presented. The unique donor acceptor structure of these block copolymers provides a rich self-assembly behavior, with the first example of a fully conjugated donor acceptor block copolymer having two separate crystalline domains being obtained.

引用

页码：16040 / 16046

页数：7

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