Synthesis and electronic properties of donor-acceptor π-conjugated siloles

被引：82
|
作者：
Boydston, AJ [1 ]
Yin, Y [1 ]
Pagenkopf, BL [1 ]
机构：
[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期
关键词：
D O I：
10.1021/ja049758z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method is presented for the synthesis of novel donor?acceptor silole chromophores through selective monohalogenation of 2,5-dimetallosiloles followed by Negishi alkyne cross-coupling reactions. The electronic properties and crystal packing of these new siloles can be controlled through judicious combinations of peripheral functional groups. Copyright © 2004 American Chemical Society.
引用
收藏
页码：3724 / 3725
页数：2
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