Glass formation via structural fragmentation of a 2D coordination network

被引：0
|
作者：
Umeyama, D. [1 ]
Funnell, N. P. [2 ]
Cliffe, M. J. [2 ]
Hill, J. A. [2 ]
Goodwin, A. L. [2 ]
Hijikata, Y. [3 ]
Itakura, T. [4 ]
Okubo, T. [5 ]
Horike, S. [1 ]
Kitagawa, S. [1 ,6 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
[3] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[4] DENSO CORP, Kariya, Aichi 4488661, Japan
[5] Kinki Univ, Sch Sci & Engn, Dept Chem, Higashiosaka, Osaka 5778502, Japan
[6] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 64期
基金：
日本科学技术振兴机构;
关键词：
THERMODYNAMIC ASPECTS; TRANSITION; LIQUIDS; POLYMERS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.
引用
收藏
页码：12728 / 12731
页数：4
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