Review-Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes

被引:585
|
作者
Schipper, Florian [1 ]
Erickson, Evan M. [1 ]
Erk, Christoph [2 ]
Shin, Ji-Yong [2 ]
Chesneau, Frederick Francois [2 ]
Aurbach, Doron [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel
[2] BASF SE, GCN E, D-67056 Ludwigshafen, Germany
关键词
X-RAY-DIFFRACTION; ELECTROCHEMICAL PERFORMANCE; STRUCTURAL-CHARACTERIZATION; INTERCALATION COMPOUNDS; ELECTRODE MATERIALS; INSERTION MATERIAL; THERMAL-STABILITY; PHASE-STABILITY; LAYERED LIMNO2; HIGH-POWER;
D O I
10.1149/2.0351701jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lithium ion batteries have become an integral part of our daily lives. Among a number of different cathode materials nickel-rich LiNixCoyMnzO2 is particularly interesting. The material can deliver high capacities of similar to 195 mAh g(-1) putting it on the map for electric vehicles. With an increasing nickel content, a number of issues arise in the material limiting its performance. The Li/Ni mixing, highly reactive surface and formation of micro cracks are the most pressing ones. An overview of recent literature exploring these phenomena is herein summarized and were applicable solutions will be highlighted. (C) The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. All rights reserved.
引用
收藏
页码:A6220 / A6228
页数:9
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