In this paper, we introduce the notion of Rota-Baxter Lie 2-algebras, which is a categorification of Rota-Baxter Lie algebras. We prove that the category of Rota-Baxter Lie 2-algebras and the category of 2-term Rota-Baxter L-8-algebras are equivalent. We introduce the notion of a crossed module of Rota-Baxter Lie algebras, and show that there is a one-to-one correspondence between strict 2-term Rota-Baxter L-8-algebras and crossed modules of Rota-Baxter Lie algebras. At last, as applications of the crossed modules of Rota-Baxter Lie algebras, we give constructions of crossed modules of pre-Lie algebras and crossed modules of Lie algebras from them.