C-N Bond Formation Using Paraformaldehyde as C1 Source - Recent Advances

被引：3
|
作者：
Guo, Zhiqiang [1 ]
Wu, Jinglong [2 ]
Wei, Xuehong [1 ]
机构：
[1] Shanxi Univ, Sci Instrument Ctr, Taiyuan 030006, Peoples R China
[2] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 01期
关键词：
Amines; C-N bonds; N-methylation reaction; Nitrogen-containing compounds; Polyformaldehyde; HYDROGEN MECHANISTIC INSIGHTS; REDUCTIVE AMINATION; NITRO-COMPOUNDS; SELECTIVE MONOMETHYLATION; DIMETHYL CARBONATE; PRIMARY AMINES; METHYLATION; METHANOL; FORMALDEHYDE; WATER;
D O I：
10.1002/ajoc.202300553
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recently, polyformaldehyde (PFA) has been used as C1 source to synthesize a series of value-added compounds due to its low price, stability, low level of toxicity and easy operation. Exploiting paraformaldehyde as C1 source, rather than using traditional methylation reagent to develop benign N-methylation reactions, can be more environment-friendly and make the chemical industry more sustainable. In this paper, the chemical transformation of polyformaldehyde and a new strategy of methylating polyformaldehyde with amine compound to methylamine compound are reviewed. These methods will provide a reference for researchers to synthesize a large number of methylamine compounds in a short reaction by using paraformaldehyde as a single carbon source.
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页数：15
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