Novel Copper Oxide Phyto-Nanocatalyst Utilized for the Synthesis of Sustainable Biodiesel from Citrullus colocynthis Seed Oil

被引:8
|
作者
Aziz, Aqsa [1 ]
Ahmad, Mushtaq [1 ,2 ]
Zafar, Muhammad [1 ]
Gaafar, Abdel-Rhman Z. [3 ]
Hodhod, Mohamed S. [4 ]
Sultana, Shazia [1 ]
Athar, Mohammad [5 ]
Ozdemir, Fethi Ahmet [6 ]
Makhkamov, Trobjon [7 ]
Yuldashev, Akramjon [8 ]
Mamarakhimov, Oybek [9 ]
Nizomova, Maxsuda [10 ]
Majeed, Salman [1 ]
Chaudhay, Bisha [1 ]
机构
[1] Quaid i Azam Univ, Dept Plant Sci, Plant Systemat & Biodivers Lab, Islamabad 45320, Pakistan
[2] Pakistan Acad Sci, Islamabad 44000, Pakistan
[3] King Saud Univ, Dept Bot & Microbiol, Coll Sci, POB 11451, Riyadh, Saudi Arabia
[4] October Univ Modern Sci & Arts, Fac Biotechnol, 6th October City 12566, Egypt
[5] Calif Dept Food & Agr, Pest Detect & Emergency Projects, 1220 N Street, 2nd Floor, Sacramento, CA 95814 USA
[6] Bingol Univ, Fac Sci & Arts, Dept Mol Biol & Genet, TR-12000 Bingol, Turkiye
[7] Tashkent State Agrarian Univ, Dept Forestry & Landscape Design, 2 A, Univ Str, Tashkent 100700, Uzbekistan
[8] Andijan State Univ, Dept Ecol & Bot, 129, Univ Str, Andijan 170100, Uzbekistan
[9] Natl Univ Uzbekistan, Dept Ecol Monitoring, 4 Univ St, Tashkent 100174, Uzbekistan
[10] Tashkent State Agrarian Univ, Dept Med Plants, 2 A, Univ Str, Tashkent 100700, Uzbekistan
关键词
biocatalyst; colocynth; green fuel; non-edible feedstock; renewable energy; WASTE COOKING OIL; RESPONSE-SURFACE; OPTIMIZATION; WATER; TRANSESTERIFICATION; NANOPARTICLES; PERFORMANCE; EMISSION; CATALYST; BIOFUEL;
D O I
10.3390/pr11061857
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The green chemistry method for nanocatalyst synthesis along with environmentally feasible non-edible sources are promising alternatives to fossil fuels. The current study focuses on the synthesis of copper oxide phyto-nanocatalyst and the identification of a new renewable feedstock, Citrullus colocynthis, to reduce environmental pollution. The highest biodiesel yield (95%) was obtained under optimum conditions of a 1:8 oil-to-methanol ratio and reaction temperature of 85 & DEG;C for 120 min with a 0.365 wt% catalyst concentration. The phyto-nanocatalyst was synthesized using seed oil cake after extracting oil with the salt of copper (copper oxide). The catalyst was then subjected to various analyses, namely, EDX, FT-IR, SEM, and XRD. The catalyst was proved to be efficient and effective after being reused five times and still there was a very small difference in biodiesel yield. All the analyses also show sustainable and stable results. Thus, copper oxide phyto-nanocatalyst with non-edible Citrullus colocynthis proved to be highly effective, sustainable, and a better alternative source to the future biodiesel industry.
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页数:22
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