Regime-Dependence of Nocturnal Nitrate Formation via N2O5 Hydrolysis and Its Implication for Mitigating Nitrate Pollution

被引：1

作者：

Ma, Pengkun ^{[1
]}

Quan, Jiannong ^{[1
]}

Dou, Youjun ^{[1
]}

Pan, Yubing ^{[1
]}

Liao, Zhiheng ^{[1
]}

Cheng, Zhigang ^{[1
]}

Jia, Xingcan ^{[1
]}

Wang, Qianqian ^{[1
]}

Zhan, Junlei ^{[2
]}

Ma, Wei ^{[2
]}

Zheng, Feixue ^{[2
]}

Wang, Yuzheng ^{[2
]}

Zhang, Yusheng ^{[2
]}

Hua, Chenjie ^{[2
]}

Yan, Chao ^{[2
,3
]}

Kulmala, Markku ^{[2
,4
]}

Liu, Yangang ^{[5
]}

Huang, Xin ^{[3
]}

Yuan, Bin ^{[6
]}

Brown, Steven S. ^{[7
]}

Liu, Yongchun ^{[2
]}

机构：

[1] Chinese Meteorol Adm, Inst Urban Meteorol, Beijing, Peoples R China

[2] Beijing Univ Chem Technol, Adv Innovat Ctr Soft Matter Sci & Engn, Aerosol & Haze Lab, Beijing 100029, Peoples R China

[3] Nanjing Univ, Sch Atmospher Sci, Joint Int Res Lab Atmospher & Earth Syst Sci, Nanjing, Peoples R China

[4] Univ Helsinki, Inst Atmospher & Earth Syst Res, Fac Sci, Helsinki, Finland

[5] Environm & Climate Sci Dept, Brookhaven Natl Lab, Upton, NY USA

[6] Jinan Univ, Inst Environm & Climate Res, Guangzhou, Peoples R China

[7] NOAA, Chem Sci Div, Earth Syst Res Lab, Boulder, CO USA

来源：

GEOPHYSICAL RESEARCH LETTERS | 2023年 / 50卷 / 24期

基金：

中国国家自然科学基金;

关键词：

N2O5; hydrolysis; regime-dependence; nocturnal nitrate formation; residual layer; mitigating nitrate pollution; PARTICULATE MATTER; REACTIVE NITROGEN; WINTER; URBAN; CHEMISTRY; EVENTS; CHINA; HAZE;

D O I：

10.1029/2023GL106183

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The heterogeneous hydrolysis of dinitrogen pentoxide (N2O5) is an important pathway in nitrate formation; however, its formation rate and relative contribution to total particulate nitrate (pNO(3)(-)) are highly variable. Here we report that nocturnal pNO(3)(-) formation via N2O5 hydrolysis is dependent on the regime defined by the ratio of NO2 to O-3. Nocturnal pNO(3)(-) formation via N2O5 hydrolysis is suppressed in an O-3-limited regime but enhanced in a NO2-limited regime. The results have crucial implications for effective control of nitrate pollution in the future. An exclusive decrease in NO2 will decrease nocturnal pNO(3)(-) formation in a NO2-limited regime but may be less effective or even increase nocturnal pNO(3)(-) formation in an O-3-limited regime.

引用

页数：10

共 36 条

[1] Wintertime nitrate formation pathways in the north China plain: Importance of N2O5 heterogeneous hydrolysis
Liu, Lang
Bei, Naifang
Hu, Bo
Wu, Jiarui
Liu, Suixin
Li, Xia
Wang, Ruonan
Liu, Zirui
Shen, Zhenxing
Li, Guohui
[J]. ENVIRONMENTAL POLLUTION, 2020, 266
[2] Fast particulate nitrate formation via N2O5 uptake aloft in winter in Beijing
Wang, Haichao
Lu, Keding
Chen, Xiaorui
Zhu, Qindan
Wu, Zhijun
Wu, Yusheng
Sun, Kang
[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2018, 18 (14) : 10483 - 10495
[3] Nocturnal fine particulate nitrate formation by N2O5 heterogeneous chemistry in Seoul Metropolitan Area, Korea
Jo, Hyun-Young
Lee, Hyo-Jung
Jo, Yu-Jin
Lee, Jong-Jae
Ban, Soojin
Lee, Jin-Ju
Chang, Lim-Seok
Heo, Gookyoung
Kim, Cheoi-Hee
[J]. ATMOSPHERIC RESEARCH, 2019, 225 : 58 - 69
[4] Effect of hydrolysis of N2O5 on nitrate and ammonium formation in Beijing China: WRF-Chem model simulation
Su, Xing
Tie, Xuexi
Li, Guohui
Cao, Junji
Huang, Rujin
Feng, Tian
Long, Xin
Xu, Ruiguang
[J]. SCIENCE OF THE TOTAL ENVIRONMENT, 2017, 579 : 221 - 229
[5] Transport Pathways of Nitrate Formed from Nocturnal N2O5 Hydrolysis Aloft to the Ground Level in Winter North China Plain
Zhao, Xiaoxi
Zhao, Xiujuan
Liu, Pengfei
Chen, Dan
Zhang, Chenglong
Xue, Chaoyang
Liu, Junfeng
Xu, Jing
Mu, Yujing
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2023, 57 (07) : 2715 - 2725
[6] Heterogeneous reaction of N2O5 on sodium nitrate aerosol
Wahner, A
Mentel, TF
Sohn, M
Stier, J
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D23) : 31103 - 31112
[7] Elevated Formation of Particulate Nitrate From N2O5 Hydrolysis in the Yangtze River Delta Region From 2011 to 2019
Zhou, Min
Nie, Wei
Qiao, Liping
Huang, Dan Dan
Zhu, Shuhui
Lou, Shengrong
Wang, Hongli
Wang, Qian
Tao, Shikang
Sun, Peng
Liu, Yawen
Xu, Zheng
An, Jingyu
Yan, Rusha
Su, Hang
Huang, Cheng
Ding, Aijun
Chen, Changhong
[J]. GEOPHYSICAL RESEARCH LETTERS, 2022, 49 (09)
[8] High N2O5 Concentrations Observed in Urban Beijing: Implications of a Large Nitrate Formation Pathway
Wang, Haichao
Lu, Keding
Chen, Xiaorui
Zhu, Qindan
Chen, Qi
Guo, Song
Jiang, Meiqing
Li, Xin
Shang, Dongjie
Tan, Zhaofeng
Wu, Yusheng
Wu, Zhijun
Zou, Qi
Zheng, Yan
Zeng, Limin
Zhu, Tong
Hu, Min
Zhang, Yuanhang
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS, 2017, 4 (10): : 416 - 420
[9] NIGHTTIME N2O5/NO3 CHEMISTRY AND NITRATE IN DEW WATER
CHANG, TY
KUNTASAL, G
PIERSON, WR
[J]. ATMOSPHERIC ENVIRONMENT, 1987, 21 (06) : 1345 - 1351
[10] A parameterization of the heterogeneous hydrolysis of N2O5 for mass-based aerosol models: improvement of particulate nitrate prediction
Chen, Ying
Wolke, Ralf
Ran, Liang
Birmili, Wolfram
Spindler, Gerald
Schroeder, Wolfram
Su, Hang
Cheng, Yafang
Tegen, Ina
Wiedensohler, Alfred
[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2018, 18 (02) : 673 - 689

← 1 2 3 4 →