Synthesis of P,P-bidentate caged phosphines via tungsten pentacarbonyl-promoted cycloaddition reactions of 1-alkyl-1,2-diphospholes

被引：0

作者：

Zagidullin, Almaz A. ^{[1
]}

Ganushevich, Yulia S. ^{[2
]}

Korchagin, Denis V. ^{[3
]}

Loennecke, Peter ^{[4
]}

Hey-Hawkins, Evamarie ^{[4
]}

Miluykov, Vasili A. ^{[1
]}

机构：

[1] RAS, FRC Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilov St, Moscow 119334, Russia

[3] Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka 142432, Moscow, Russia

[4] Univ Leipzig, Inst Inorgan Chem, D-04103 Leipzig, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 2024年 / 48卷 / 15期

基金：

俄罗斯科学基金会;

关键词：

DIELS-ALDER REACTION; THERMAL DIMERIZATION; COORDINATION SPHERE; INTRAMOLECULAR EXCHANGE; ASYMMETRIC-SYNTHESIS; CRYSTAL-STRUCTURES; COMPLEXES; 1-(+)-NEOMENTHYL-1,2-DIPHOSPHOLE; 1-PHENYL-3,4-DIMETHYLPHOSPHOLE; CHEMISTRY;

D O I：

10.1039/d3nj05665a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Utilizing the W(CO)(5) group as a promoter, we have established a straightforward pathway for the conversion of simple 1-alkyl-1,2-diphospholes to P,P-bidentate caged phosphines via [4+2] cycloaddition reactions. Furthermore, during the course of our investigation, we have observed a rare instance of isomerization, wherein the W(CO)(5) migrates between the two phosphorus atoms in pentacarbonyl(1-alkyl-1,2-diphosphole)tungsten(0). This intriguing phenomenon has been thoroughly investigated using variable-temperature P-31 NMR spectroscopy.

引用

页码：6848 / 6856

页数：9

共 3 条

[1] Versatile Cycloaddition Reactions of 1-Alkyl-1,2-Diphospholes
Zagidullin, Almaz
Ganushevich, Yulia
Miluykov, Vasili
Sinyashin, Oleg
Hey-Hawkins, Evamarie
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2013, 188 (1-3) : 238 - 242
[2] Cycloadducts of 1-Alkyl-1,2-diphospholes with N-Phenylmaleimide: Synthesis, Structure, Oxidation, and Thionation Reactions
Zagidullin, Almaz
Miluykov, Vasili
Sinyashin, Oleg
Loennecke, Peter
Hey-Hawkins, Evamarie
[J]. HETEROATOM CHEMISTRY, 2014, 25 (01) : 28 - 34
[3] Controllable synthesis of P-chiral 1,2-and 1,3-diphosphines via asymmetric Diels-Alder reactions involving functionalized allylic phosphines as dienophiles
Yuan, Mingjun
Pullarkat, Sumod A.
Yeong, Crystal Huixian
Li, Yongxin
Krishnan, Deepa
Leung, Pak-Hing
[J]. DALTON TRANSACTIONS, 2009, (19) : 3668 - 3670

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