Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

被引：0
|
作者：
Grishin, A. V. [1 ]
Filippov, I. P. [1 ]
Rostovskii, N. V. [1 ]
机构：
[1] St Petersburg Univ, St Petersburg 199034, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2024年 / 94卷 / SUPPL 1期
基金：
俄罗斯科学基金会;
关键词：
2H-azirines; rhodium(II) acetate; metal complex; spectroscopy; X-ray diffraction analysis; CRYSTAL; TETRAACETATE; CHEMISTRY; ADDUCTS; LIGANDS;
D O I：
10.1134/S107036322414007X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Complexes of rhodium(II) acetate with 2H-azirines were obtained for the first time. The 1 : 2 complexes were characterized using H-1 and C-13 NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh-2(OAc)(4) complex with two 3-(4-methoxyphenyl)-2H-azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the C-i point group.
引用
收藏
页码：S47 / S52
页数：6
相关论文
共 50 条
  • [1] Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines
    A. V. Grishin
    I. P. Filippov
    N. V. Rostovskii
    [J]. Russian Journal of General Chemistry, 2024, 94 : S47 - S52
  • [2] Recent approaches to the synthesis of 2H-azirines
    Nagarajan Ramkumar
    Leonid G. Voskressensky
    Upendra K. Sharma
    Erik V. Van der Eycken
    [J]. Chemistry of Heterocyclic Compounds, 2019, 55 : 795 - 801
  • [3] Recent approaches to the synthesis of 2H-azirines
    Ramkumar, Nagarajan
    Voskressensky, Leonid G.
    Sharma, Upendra K.
    Van der Eycken, Erik V.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2019, 55 (09) : 795 - 801
  • [4] A GENERAL SYNTHESIS OF 2H-AZIRINES FROM OLEFINS . FUSED AZIRINES
    HASSNER, A
    FOWLER, FW
    [J]. TETRAHEDRON LETTERS, 1967, (16) : 1545 - &
  • [5] 2H-Azirines as dipolarophiles
    Melo, TMVDPE
    Cardoso, AL
    Gomes, CSB
    Gonsalves, AMDR
    [J]. TETRAHEDRON LETTERS, 2003, 44 (33) : 6313 - 6315
  • [6] 2H-Azirines: Recent Progress in Synthesis and Applications
    Xu, Fen
    Zeng, Fan-Wang
    Luo, Wen-Jie
    Zhang, Shi-Yu
    Huo, Jia-Qi
    Li, Ya-Peng
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (11)
  • [7] A simple green procedure for the synthesis of 2H-azirines
    Singh, PND
    Carter, CL
    Gudmundsdóttir, AD
    [J]. TETRAHEDRON LETTERS, 2003, 44 (35) : 6763 - 6765
  • [8] NICKEL(II)-CATALYZED SYNTHESIS OF PYRROLES FROM 2H-AZIRINES AND ACTIVATED KETONES
    FARIADOSSANTOSFILHO, P
    SCHUCHARDT, U
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (09): : 647 - 648
  • [9] REACTION OF 2H-AZIRINES WITH NITRONES
    PADWA, A
    CROSBY, K
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (17): : 2651 - 2653
  • [10] SYNTHESIS OF PYRROLES, PYRIDINES, AND AZEPINES FROM 2H-AZIRINES
    SARUWATARI, M
    HATANO, S
    ISOMURA, K
    TANIGUCHI, H
    [J]. HETEROCYCLES, 1980, 14 (01) : 125 - 125
12345