Enhanced basicity of an electron donor-acceptor complex

被引：1

作者：

Stevenson, Bernard G. G. ^{[1
]}

Prascsak, Amanada V. V. ^{[2
]}

Lee, Annemarie A. A. ^{[1
]}

Talbott, Eric D. D. ^{[1
]}

Fredin, Lisa A. A. ^{[2
]}

Swierk, John R. R. ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, 4400 Vestal Pkwy East, Binghamton, NY 13902 USA

[2] Lehigh Univ, Dept Chem, 6 E Packer Ave, Bethlehem, PA 18015 USA

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 20期

关键词：

Complex forms - Electron donor acceptor complex - Photoredox reactions - Proton acceptors - Reanalysis;

D O I：

10.1039/d2cc05985a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the alpha-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the alpha-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.

引用

页码：2943 / 2945

页数：3

共 50 条

[1] THE BIMOLECULAR MODEL OF A TRIMOLECULAR ELECTRON DONOR-ACCEPTOR COMPLEX
BUDYKA, MF
GAVRISHOVA, TN
LAUKHINA, OD
[J]. MENDELEEV COMMUNICATIONS, 1995, (05) : 205 - 206
[2] Oscillatory fluorescence decay of an electron donor-acceptor complex
Rubtsov, IV
Yoshihara, K
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (35): : 6138 - 6140
[3] ELECTRON-TRANSFER DYNAMICS IN A DONOR-ACCEPTOR COMPLEX
MAY, V
SCHREIBER, M
[J]. CHEMICAL PHYSICS LETTERS, 1991, 181 (2-3) : 267 - 273
[4] THERMODYNAMICS OF EXCITED ELECTRON DONOR-ACCEPTOR COMPLEX FORMATION
KNIBBE, H
REHM, D
WELLER, A
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1969, 73 (8-9): : 839 - &
[5] ELECTRON DONOR-ACCEPTOR COMPLEXES
FOSTER, R
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (17): : 2135 - 2141
[6] ELECTRON DONOR-ACCEPTOR COUPLES
ONDRECHEN, MJ
[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1995, 14 (01) : 1 - 14
[7] DONOR-ACCEPTOR COMPLEX IN GAAS
REYNOLDS, DC
ALMASSY, RJ
LITTON, CW
MCCOY, GL
NAM, SB
[J]. BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1978, 23 (03): : 224 - 224
[8] CATALYTIC ACTIVITY OF ELECTRON DONOR-ACCEPTOR COMPLEX OF POLYNAPHTHOQUINONE WITH POTASSIUM
IWASAWA, Y
TAMARU, K
ONISHI, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (19) : 1051 - &
[9] Radical Alkynyltrifluoromethylation of Alkenes Initiated by an Electron Donor-Acceptor Complex
Jiang, Heng
He, Yanyan
Cheng, Yuanzheng
Yu, Shouyun
[J]. ORGANIC LETTERS, 2017, 19 (05) : 1240 - 1243
[10] Tetrachlorophthalimides as Organocatalytic Acceptors for Electron Donor-Acceptor Complex Photoactivation
Zhou, Wei
Wu, Shuo
Melchiorre, Paolo
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (20) : 8914 - 8919

← 1 2 3 4 5 →