Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides

被引：2

作者：

Shen, Mei-Hua ^{[1
]}

Qi, Xiao-Wen ^{[1
]}

Li, De-Xia ^{[1
]}

Wang, Xin-Yi ^{[1
]}

Zhu, Chi-Fan ^{[1
]}

Xu, Hua-Dong ^{[1
]}

机构：

[1] Changzhou Univ, Sch Pharm, Changzhou 213164, Jiangsu, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 12期

关键词：

UNACTIVATED OLEFINS; CLICK CHEMISTRY; ORGANIC AZIDES; CARBON BONDS; HYDROHYDRAZINATION; COMPLEXES; HYDROFUNCTIONALIZATION; HYDROALKOXYLATION; HYDROAMINATION; DIVERSITY;

D O I：

10.1039/d3qo00431g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new cobalt-catalyzed hydroazidation of 1-aryl-1,3-dienes by using TMSN3 as a nucleophilic azide source under mild conditions has been reported, leading to the synthesis of a wide range of allylic azides with moderate to good yields. This oxidative MHAT hydroazidation achieved excellent regioselectivity towards 1,2-addition products through an S(N)2-like pathway between in situ generated allyl cobalt(iv) species and TMSN3.

引用

页码：3010 / 3015

页数：6

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