Exploring the Effect of Low-Temperature Oxidation on the Petrophysical Characteristics of Coal

被引:0
|
作者
Li, He [1 ]
Cao, Jieyan [1 ]
Lu, Jiexin [1 ]
Lu, Yi [1 ]
Shi, Shiliang [1 ]
Wang, Zheng [1 ]
Guo, Xin [1 ]
Ye, Qing [1 ]
机构
[1] Hunan Univ Sci & Technol, Sch Resource Environm & Safety Engn, Xiangtan 411201, Hunan, Peoples R China
来源
ACS OMEGA | 2023年 / 8卷 / 43期
基金
中国国家自然科学基金;
关键词
FRACTAL CHARACTERISTICS; FUNCTIONAL-GROUPS; SPONTANEOUS COMBUSTION; BITUMINOUS COAL; DEFORMED COALS; PORE STRUCTURE; FREE-RADICALS; MECHANISM; APPLICABILITY; ADSORPTION;
D O I
10.1021/acsomega.3c05389
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Low-temperature oxidation leads to the accumulation of heat in coal, and it is an important trigger for coal spontaneous combustion (CSC). The oxidation effects induce irreversible damage in the pore and fracture structures of coal, which provide a way for the infiltration of oxygen. In this work, the evolution of pores and cracks of coal in the progress of low-temperature oxidation is researched based on nitrogen adsorption, scanning electron microscopy (SEM), and ultrasonic testing. The results show that the oxidation effect increases microporous structures and promotes the development of mesopores and macropores in coal. Besides, as the temperature increases, the oxidation effect becomes more significant, while the pore morphology has not changed significantly yet. Meanwhile, the oxidation effect causes coal particles to block or collapse in the macropores, and the plugging degree increases with increasing temperature.
引用
收藏
页码:40572 / 40586
页数:15
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