Investigate the suitability of g-C3N4 nanosheets ornamented with BiOI nanoflowers for photocatalytic dye degradation and PEC water splitting

被引:31
|
作者
Velusamy, P. [1 ,2 ]
Liu, Xinghui [1 ,3 ]
Sathiya, M. [4 ]
Alsaiari, Norah Salem [5 ]
Alzahrani, Fatimah Mohammed [5 ]
Nazir, M. Tariq [6 ]
Elamurugu, Elangovan [7 ]
Pandian, M. Senthil [8 ]
Zhang, Fuchun [1 ]
机构
[1] Yanan Univ, Sch Phys & Elect Informat, Yanan 716000, Peoples R China
[2] Thiagarajar Coll Engn, Dept Phys, Madurai 625015, Tamil Nadu, India
[3] Saveetha Inst Med & Tech Sci SIMTS, Saveetha Sch Engn, Dept Mat Phys, Chennai 602105, Tamilnadu, India
[4] Madurai Kamaraj Univ, Thiagarajar Coll, Dept Chem, Madurai 625009, Tamil Nadu, India
[5] Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 11671, Riyadh 84428, Saudi Arabia
[6] Univ New South Wales, Sch Mfg Engn, Sydney, NSW 2052, Australia
[7] SRM Inst Sci & Technol, Coll Engn & Technol, Dept Phys & Nanotechnol, iDARE Lab, Chennai 603203, Tamilnadu, India
[8] SSN Coll Engn, Res Ctr, Chennai 603110, Tamil Nadu, India
基金
中国国家自然科学基金;
关键词
Nano-heterostructure; PEC; Solvothermal synthesis; Methyl red; Pollutant degradation; HETEROJUNCTION; CARBON; HYDROGEN;
D O I
10.1016/j.chemosphere.2023.138007
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The two-step thermal polymerization and solvothermal approach is used to construct nano heterostructures of FCN and BiOI (bismuth oxeye iodide), both of which are Nobel metal-free materials. This work reports the effect nano-heterostructure on the micro-structural, light absorption capability, PEC properties and pollutant degra-dation efficiency of the synthesised heterostructures. The addition to that formation of FCN/BiOI nano-heterostructure enhances the solar light absorption. The FCN/BiOI nano heterostructure shows 10 times higher photocurrent density than the BCN nanostructure and 3.8 time higher that FCN. The FCN/BiOI has a high induced photo-current density (20.17 mA/cm2) and H2 evolution rate (3762 mu mol h-1 cm -2) under solar light illumination (lambda >= 420 nm) in comparison with the other. Furthermore, the photocatalytic performance of this material for the breakdown of methyl red dyes was much greater. Under solar light irradiation, the azo dyes were degraded in 90 min. The FCN/BiOI nano-heterostructure has a higher dye degradation efficiency of 97.91%. The rapid transport of photo-induced electrons in the FCN/BiOI nanocomposite is responsible for the improvement in PEC and PC performances. These impressive findings suggest that this nanocomposite might be used to facilitate the PEC water splitting and the PC degradation of MR in the presence of light. The current research provides insight on how to best tailor composition and structure for efficient FCN photo-electrocatalysis water splitting and Methyl red dye degradation.
引用
收藏
页数:12
相关论文
共 50 条
  • [1] Zinc iron selenide nanoflowers anchored g-C3N4 as advanced catalyst for photocatalytic water splitting and dye degradation
    Mohan, Harshavardhan
    Ha, Ga Hyeon
    Oh, Hyeon Seung
    Kim, Gitae
    Shin, Taeho
    CHEMOSPHERE, 2022, 307
  • [2] The g-C3N4 Nanosheets Separated by PS for Photocatalytic Degradation of Dye
    Yu, Qingbo
    Fang, Songhui
    Wang, Xiaoze
    JOURNAL OF NANO RESEARCH, 2017, 49 : 215 - 224
  • [3] Photocatalytic and Photoelectrocatalytic Water Splitting by Porous g-C3N4 Nanosheets for Hydrogen Generation
    Mehtab, Amir
    Alshehri, Saad M.
    Ahmad, Tokeer
    ACS APPLIED NANO MATERIALS, 2022, 5 (09) : 12656 - 12665
  • [4] Enhanced Photocatalytic Degradation of Antibiotics by Ag/BiOI/g-C3N4 Composites
    Li, Ting
    Ma, Mengzhou
    Wang, Junhai
    Li, Qiang
    Yu, Yunwu
    Zou, Qianqian
    Li, Xinran
    Wei, Xiaoyi
    Yan, Tingting
    Tang, Yulan
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2023, 220 (17):
  • [5] Making g-C3N4 ultra-thin nanosheets active for photocatalytic overall water splitting
    Wu, Chunzheng
    Xue, Shengyang
    Qin, Zhaojun
    Nazari, Masoumeh
    Yang, Guang
    Yue, Shuai
    Tong, Tian
    Ghasemi, Hadi
    Hernandez, Francisco C. Robles
    Xue, Sichuang
    Zhang, Di
    Wang, Haiyan
    Wang, Zhiming M.
    Pu, Shengyan
    Bao, Jiming
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 282
  • [6] The CoSx-modified g-C3N4 nanosheets towards photocatalytic water splitting hydrogen production enhancement
    Pan, Jiaqi
    Mei, Jie
    Li, Hongli
    Wang, Beibei
    Wang, Jingjing
    Song, Changsheng
    Zheng, Yingying
    Li, Chaorong
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (02) : 2385 - 2394
  • [7] The CoSx-modified g-C3N4 nanosheets towards photocatalytic water splitting hydrogen production enhancement
    Jiaqi Pan
    Jie Mei
    Hongli Li
    Beibei Wang
    Jingjing Wang
    Changsheng Song
    Yingying Zheng
    Chaorong Li
    Journal of Materials Science: Materials in Electronics, 2021, 32 : 2385 - 2394
  • [8] PHOTOCATALYTIC DEGRADATION OF NORFLOXACIN ON CdS/g-C3N4 COMPOSITES IN WATER
    Lai, Guoqiang
    Yang, Jie
    Wu, Zanen
    Wu, Shibiao
    Chen, Xia
    Ge, Yejun
    Li, Yaru
    Wang, Yaqin
    FRESENIUS ENVIRONMENTAL BULLETIN, 2022, 31 (10): : 10419 - 10427
  • [9] Supramolecular Precursor Strategy to Construct g-C3N4/Silica Hybrid Nanosheets for Photocatalytic Degradation of Dye and Antibiotic Pollutants
    Yu, Yongsheng
    Wang, Jinghan
    Yan, Zhaoli
    Jing, Qiangshan
    Liu, Peng
    Xu, Bing
    NANOMATERIALS, 2022, 12 (18)
  • [10] A review on g-C3N4 incorporated with organics for enhanced photocatalytic water splitting
    Liang, Jinnan
    Yang, Xiaohong
    Wang, Yan
    He, Peng
    Fu, Haitao
    Zhao, Yue
    Zou, Qingchuan
    An, Xizhong
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (22) : 12898 - 12922