Role of the intercalated ions on the high capacitance behavior of Ti3C2Tx MXene nanohybrids

被引:1
|
作者
Koneru, Bhargavi [1 ]
Swapnalin, Jhilmil [1 ]
Pothu, Ramyakrishna [2 ]
Banerjee, Prasun [1 ]
Boddula, Rajender [3 ]
Radwan, Ahmed Bahgat [3 ]
Al-Qahtani, Noora [3 ,4 ]
机构
[1] GITAM Univ, Gandhi Inst Technol & Management, Multiferro & Magnet Mat Res Lab, Bengaluru, Karnataka, India
[2] Hunan Univ, Coll Chem & Chem Engn, Sch Phys & Elect, Changsha, Peoples R China
[3] Qatar Univ, Ctr Adv Mat CAM, Doha, Qatar
[4] Qatar Univ, Cent Lab Unit CLU, Doha, Qatar
关键词
MXene; surface terminations; supercapacitor; intercalated ions; 2D materials; nanoplating; nanohybrids; MAX PHASE; CHALLENGES; ELECTRODES; STABILITY; PROGRESS; TI3ALC2;
D O I
10.1080/20550324.2023.2258622
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ti3C2Tx (MXene) is prone to surface oxidation because of the presence of oxygen surface terminals in its surfaces. In this work, the effect of oxygen surface terminals has been reduced by replacing it with other surface terminals or thin layers of heteroatom at the interlayers. These resulted in increasing the interlayer spacing from 9.3 angstrom up to 12.5 angstrom with better flexibility properties, thereby facilitating electron/mass transports by exposing enough active surface areas. The carbon nanoplated MXene showed enhanced specific capacitance of 110 F/g at 2 mV/s in LiOH electrolytes for superior supercapacitor applications.
引用
收藏
页码:128 / 137
页数:10
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