Investigating the effectiveness of rice husk-derived low-cost activated carbon in removing environmental pollutants: a study of its characterization

被引:5
|
作者
Kaya, Nihan [1 ]
Ozkeser, Esma Carus [2 ]
Uzun, Zeynep Yildiz [3 ]
机构
[1] Ondokuz Mayis Univ, Dept Chem Engn, Samsun, Turkiye
[2] Hitit Univ, Dept Chem Engn, Corum, Turkiye
[3] Sinop Univ, Dept Chem & Chem Proc Technol, Sinop, Turkiye
关键词
Adsorption; CO2; capture; KOH-activated biochar; methyl red; pyrolysis; rice husk; METHYL-RED; SUGARCANE BAGASSE; CO2; CAPTURE; WASTE-WATER; BIOCHAR; ADSORPTION; PYROLYSIS; BIOMASS; SHELL; BLUE;
D O I
10.1080/15226514.2023.2246584
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The chemically activated biochar was produced through the pyrolysis of rice husk. Thermal gravimetric and elemental analysis were conducted to characterize the raw rice husk. The activated biochar product underwent evaluation through SEM, BET and, FT-IR analysis. This cost-effective activated carbon was utilized as an adsorbent for the elimination of environmental pollutants. At a temperature of 25 & DEG;C, the activated biochar product exhibited an impressive maximum CO2 adsorption capacity of 152 mg/g. This exceptional performance can be attributed to its notable surface area and porosity, measuring at 2,298 m(2)/g and 0.812 cm(3)/g, respectively. This product was also utilized to remove methyl red (MR) dye from an aqueous solution. The optimal parameters for the removal of MR were determined as follows: a pH of 6.0, a temperature of 25 & DEG;C, an initial MR concentration of 50 mg/L, and an adsorbent dosage of 0.4 g/L. At a duration of 140 min, the system attained its maximum equilibrium adsorption capacity, reaching a value of 62.06 mg/g. Furthermore, the calculated maximum MR removal efficiency stood at an impressive 99.31%. The thermodynamic studies demonstrated that the MR removal process was spontaneous, exothermic, and increased randomness. Kinetic studies suggested that the pseudo-second-order model can fit well. Novelty statementRice is the staple food for a significant portion of the world's population. Rice husk, which is released during the production and processing of rice, is one of the most important agricultural wastes worldwide. In this study, low cost activated carbon was produced by converting renewable resource such as rice husk biomass into a product with high added value. The resulting product, with its high surface area, can offer a more sustainable, cost-effective, and versatile alternative for a range of industrial, environmental, and medical applications.
引用
收藏
页码:427 / 447
页数:21
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