Ferroelectric BaTaO2N perovskite - Towards structure-property relationship study on high-quality crystals and ceramics prepared with the aid of liquid phase

被引：4

作者：

Hosono, Akira ^{[1
]}

Masubuchi, Yuji ^{[2
]}

Higuchi, Mikio ^{[2
]}

Kikkawa, Shinichi ^{[2
]}

机构：

[1] Hokkaido Univ, Grad Sch Chem Sci & Engn, N13 W8,Kita Ku, Sapporo 0608628, Japan

[2] Hokkaido Univ, Fac Engn, N13 W8,Kita Ku, Sapporo 0608628, Japan

来源：

SOLID STATE SCIENCES | 2023年 / 144卷

基金：

日本学术振兴会;

关键词：

Perovskite-type oxynitride; Dielectric; Single crystal; Ceramics; DIELECTRIC OXYNITRIDE PEROVSKITES; SPARK PLASMA; SINGLE-CRYSTALS; ELECTROPHORETIC DEPOSITION; LATIO2N; GROWTH; TANTALUM; SRTAO2N; BA; TA;

D O I：

10.1016/j.solidstatesciences.2023.107310

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ternary metal oxynitride compound, perovskite-type BaTaO2N, has been a subject of interest for solid-state physicists and chemists. The notable dielectric property has been reported in a centrosymmetric average structure although the anisotropic anion configuration is preferable in cis-TaO4N2 octahedra around Ta5+ with d0 electron state. Either single crystals or sintered ceramics in high quality is necessary to clarify the puzzle between the structure and property. Thin film studies are sometimes misleading and confusing. This report reviews the preparation of BaTaO2N in high quality from the viewpoints of its crystal growth in a liquid phase, sintering in a thick ceramic form, and low-temperature and short time sintering with a liquid phase additive to obtain the highquality samples for investigation of the structure-dielectric property relationship.

引用

页数：10